
Humulene, also known as α-humulene or α-caryophyllene, is one of the components of the essential oil from the flowering cone of the hops plant. It’s a naturally occurring terpene, first found in hops (Humulus lulupus) from which it derives its name. It’s an isomer of β-caryophyllene, and the two are often found together as a mixture in many aromatic plants including pine trees, orange trees, marsh elders, tobacco, and sunflower plants. Humulene is also found in sage, basil, cloves, Japanese spicebush, ginseng, mint, ginger, Vietnamese coriander and cannabis.
The concentration of humulene varies among different varieties of hops but can be up to 40% of the essential oil. Humulene and its reaction products in the brewing process of beer gives many beers their earthy, woody, piney, “hoppy” aroma. It has been said that noble hop varieties have been found to have higher levels of humulene, while other bitter hop varieties contain low levels.
The ratio of humulene to caryophyllene varies from one hop variety to another, but many brewers consider a good aroma to be one that has a ratio of greater than 3:1. Such hops tend to be floral, herbal, and spicy in character.
Some varieties, such as Hallertauer Mittelfrüh and U.K. Kent Golding, may contain 30% or more of their essential oils in humulene, but, because humulene is highly volatile and hydrophobic, only trace quantities of it may actually reach the final beer. Oxidation products of humulene, on the other hand, especially humulene mono-and di-epoxides, can impart significant amounts of aroma to beer. Humulene epoxide III is one of the most potent flavor compounds in Hallertauer Mittelfrüh, for instance, a variety that is high in humulene but relatively low in total oils.
Allowing hops that are high in humulene to age in bales for several weeks prior to pelletizing will result in greater amounts of humulene epoxides, as well as other hop oil oxidation products, which some brewers believe can significantly increase the hops’s aroma potential.
Which hops have the most humulene? Below is a table which ranks hops in terms of their humulene content as a percentage of the total oil content.
Variety | Humulene % | Aroma Wheel Placement | Description |
Vanguard | 51.1 | Floral, Herbal | Herbal and floral tones |
Admiral (UK) | 46.87 | Citrus, Tobacco/Earthy, Herbal | Pleasant, resinous hop aroma with hints of citrus (orange) and herbal flavors |
EKG (UK) | 45.95 | Floral, Spicy, Tobacco/Earthy | Smooth and delicate with floral, lavender, spice, honey, earth, lemon and thyme overtones |
Perle (GR) | 40.38 | Fruity, Floral, Spicy | Delicate floral, fruit, spice and mint tones |
WGV (UK) | 40.36 | Floral, Tobacco/Earthy, Herbal | Fresh earthy, botanical and floral flavors |
Golding | 39.84 | Floral, Spicy | Mild and delicate with sweet floral characteristics |
Liberty | 37.86 | Citrus, Spicy | Mild and spicy with subtle lemon and citrus characteristics |
Fuggle | 36.37 | Fruity, Tobacco/Earthy | Mild wood and fruit characteristics |
Hallertau (GR) | 36.18 | Mild, yet spicy, with floral and citrus tones | |
Perle | 35.28 | Floral, Spicy, Herbal | Slightly spicy with herbal and floral characteristics |
Tettnang | 33.59 | Spicy | Noble aroma that is pleasant and spicy |
Willamette | 33.03 | Floral, Spicy | Mild and pleasant, with slightly spicy and floral tones |
Northern Brewer (GR) | 32.41 | Floral, Herbal | Medium intense herbal and floral tones |
Hallertau | 32.39 | Floral, Spicy, Herbal | Mild and pleasant, yet spicy, with herbal and floral characteristics |
Styrian Celeia | 32.13 | Floral | Pleasant and hoppy, similar to traditional European varieties |
Magnum | 31.21 | No distinct aroma characteristics | |
Brewers Gold (GR) | 30.48 | Fruity, Spicy | Black currant, fruit and spice characteristics |
Northern Brewer | 29.44 | Tobacco/Earthy, Pine | Medium intensity, pine and mint characteristics |
Glacier | 29.08 | Herbal | Pleasant hop aroma |
Saaz | 28.18 | Spicy, Tobacco/Earthy | Mild spice and earth tones |
Tettnang (GR) | 27.12 | Floral, Tobacco/Earthy, Herbal | Mild and pleasant with balanced earthy, herbal and floral aroma impressions |
Mt. Hood | 26.8 | Spicy, Tobacco/Earthy, Herbal | Mild, herbal and somewhat pungent or spicy |
Crystal | 26.58 | Spicy | Mild, spicy and floral |
Santiam | 25.81 | Floral, Spicy, Herbal | Slightly spicy with herbal and floral characteristics |
Herkules (GR) | 25.62 | Floral | Spicy, floral and hop notes with hints of pine, black pepper and melon |
Styrian Aurora | 24.16 | Floral, Pine | Intense and pleasant displaying floral, pine and hoppy characteristics |
Sorachi Ace | 22.62 | Citrus, Herbal, Grassy | Unique lemon and dill characteristics |
Yakima Gold | 22.62 | Mild and pleasant | |
Millenium | 22.2 | Floral, Tobacco/Earthy, Herbal | Mild and resinous with floral and herbal tones |
Ahtanum | 20.69 | Citrus, Floral, Tobacco/Earthy | Floral, earthy, citrus and grapefruit tones |
Sterling | 19.33 | Citrus, Spicy | Herbal and spicy, with a hint of floral, citrus (lemon/pineapple) characteristics |
Summit | 19.21 | Citrus, Spicy, Tobacco/Earthy | Distinct spice, earthy, onion, garlic and citrus (pink grapefruit, orange and tangerine) tones |
Equinox | 19.07 | Citrus, Herbal, Tropical Fruit | A pronounced aroma profile with citrus, tropical fruit, floral and herbal characteristics. Specific descriptors include lemon, lime, papaya, apple, and green pepper. |
Bullion | 18.84 | Fruity | Strong and zesty blackcurrant characteristics |
Cluster | 18.82 | Floral, Spicy | Strong floral and spicy characteristics |
Nugget | 18.8 | Spicy, Herbal | Mild and pleasant with spicy, herbal tones |
Chinook | 18.35 | Citrus, Spicy, Pine | Distinct, medium intensity spice and pine characteristics with subtle notes of grapefruit |
Mt. Rainier | 17.92 | Citrus, Floral, Spicy | Floral and noble aromas, with citrus and licorice overtones |
Amarillo | 17.9 | Citrus, Floral, Tropical Fruit | Floral, tropical, and citrus (lemon, orange and grapefruit) characteristics |
Simcoe | 17.42 | Citrus, Tobacco/Earthy, Pine | Unique passionfruit, pine, earth and citrus characteristics |
Newport | 17.32 | Mild | |
Horizon | 16.36 | Floral, Spicy | Pleasant and spicy, with floral characteristics |
Warrior | 16.03 | Citrus, Herbal, Pine | Mild and resinous with subtle citrus, pine and herbal characteristics |
Brewers Gold | 15.65 | Fruity, Spicy | Spicy, fruity characteristics, black currant |
Brewers Delight | 15.22 | ||
Palisade | 14.89 | Stone Fruit, Herbal, Grassy | Apricot, grass and clean floral charcteristics |
Cascade | 14.19 | Fruity, Citrus, Floral | Medium intense floral, citrus and grapefruit tones |
Galena | 13.53 | Citrus, Stone Fruit, Spicy | Spicy, blackcurrant and citrus (grapefruit) tones |
Bitter Gold | 13.49 | No specific aroma characteristics | |
Chelan | 12.66 | Citrus, Floral | Mild floral and citrus characteristics |
Ultra | 12.53 | Floral, Spicy | Mild and pleasant with spicy, floral tones |
Columbus | 11.99 | Citrus, Spicy | Pungent, black pepper, licorice characteristics with subtle citrus overtones |
Tahoma | 11.68 | Citrus, Cedar, Pine | Predominate citrus and lemon notes with cedar, pine, floral, pepper and subtle green melon notes. |
Centennial | 10.68 | Citrus, Floral | Medium intensity floral and citrus (lemon) tones |
Mosaic | 10.62 | Citrus, Floral, Grassy | A complex array of tropical fruit, citrus, berry, herbal, earthy and pine characteristics |
Bravo | 8.97 | Fruity, Floral | Pleasant fruity and floral aroma characteristics |
Citra | 8.73 | Fruity, Citrus, Tropical Fruit | Strong citrus and tropical tones of grapefruit, melon, lime, gooseberry, passion fruit and lychee |
Triplepearl | 7.2 | Pleasant and balanced with notes of melon, orange citrus, resin, spice and pepper |